I like Charlie Rose, he is friendly and interested and knowledgeable, and he has some interesting guests, like:
Warren Buffet, Bill and Melinda Gates
The "Daily Llama"
(Some of these interviews begin and end in the middle of things.)
Hey, Conan just said what I've been saying: "we're in a golden era of TV"!
I see that the John Travolta interview, one of the world's most popular actors, has been there over a year, and it's had less than a thousand views! Perhaps this explains the superficial normal talk show format: most people won't sit still for an hour's in-depth talk?
Update: Hunter S Thompson
I think this one mainly shows that if you do lots of drugs, it hurts your mental and vocal abilities.
The second half though has Isabella Rossellini, who wrote a book. She is cute and has a mind. Her face is fantastic, she is one of those women who can pull off a very short hair style.